An Unprecedented Use for Glycerol: Chemoselective Reducing Agent for Sulfoxides†

نویسندگان

  • Nuría García
  • Patricia García-García
  • Manuel A. Fernández-Rodríguez
  • Daniel García
  • María R. Pedrosa
  • Francisco J. Arnáiz
  • Roberto Sanz
چکیده

A new application for glycerol that expands its possibilities apart from green solvent and precursor of value-added products has been demonstrated. Simple, easily available, and environmentally friendly dioxomolybdenum(VI) complexes are highly efficient catalysts for the chemoselective sulfoxide deoxygenation with this biomass-derived chemical feedstock. Both refined glycerol and crude glycerin 10

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تاریخ انتشار 2013